Theories of Hydrophobic Effects and the Description of Free Volume in Complex Liquids

Physics – Chemical Physics

Scientific paper

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14 pages included 3 figures; submitted to the proceedings of the NATO Advanced Study Institute: New Approaches to Old and New

Scientific paper

Recent progress on molecular theories of hydration of nonpolar solutes in
aqueous solution has led to new ways of thinking about the old issue of free,
or "available," volume in liquids. This article surveys the principal new
results with particular attention to general issues of packing in liquids.

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