Manganese oxides as high-pɛ redox buffers on Mars

Details Manganese oxides as high-pɛ redox buffers on Mars Manganese oxides as high-pɛ redox buffers on Mars

Feb 1984

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1984icar...57..307b&link_type=abstract

Icarus, Volume 57, Issue 2, p. 307-312.

Physics

Scientific paper

The X-ray photoelectron spectrum of Mn(VI) is closely similar to that of UV-irradiated MnO2, previously reported to simulate the Viking gas exchange reaction. β-MnO2 is the thermodynamically stable form of manganese on the surface of Mars, and MnO2 abundances estimated from shergottite, nakhlite, and chassignite iron/manganese ratios are sufficient to account for the oxidant buffer capacity observed by Viking.

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