Transition probabilities and Franck-Condon factors for the second negative band system of O2(+)

Physics

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Franck-Condon Principle, Molecular Ions, Oxygen Ions, Positive Ions, Transition Probabilities, Dipole Moments, Spectral Bands, Vibrational Spectra

Scientific paper

Transition probabilities for the second negative band system of O2(+) are computed using the dipole transition moment presented by Wetmore et al. (1984). Vibrational levels v double prime = 0 - 54 of the X2Pi(g) ground state and v prime = - 33 of the excited A2Pi(u) state are included. Franck-Condon factors for ionization-excitation of O2 to O2(+) are also presented.

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