The Forbidden Lines in the High Frequency Discharge of Mercury, Cadmium, and Zinc.

Physics

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Scientific paper

IN addition to the observed results of the intensity modification of spectra in the high frequency discharge in mercury, we have found the forbidden lines 1S-2p1 of mercury and 1S-2p1 and 1S-2p3 of cadmium with moderate intensities. The quartz tube was 15 cm. long and 2 cm. in diameter, and the pressure of vapours was kept at about 0.001 mm. mercury. The spectra were excited with external electrodes by a 10-metre oscillator, and observed in it, end on. Heating the tube caused the discharge to become brighter, and a remarkable intensity modification was observed in mercury, as is seen from the reproduction of the microphotometric records of the spectra at 70° C. and at room temperature (Fig. 1). It can be seen that the effects of a slight rise of temperature are: (1) the vapour emits only the series lines, while spark lines appear at room temperature; (2) the intensities of the series lines decrease quite regularly with the increase of the number of the members; (3) the forbidden line 1S-2p1 enhances more than the neighbouring triplet lines 2p2-12d and 2p2-13d.

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