Van-der-Waals-interaction constant

Details Van-der-Waals-interaction constant Van-der-Waals-interaction constant

Jan 1997

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1997aipc..386..231n&link_type=abstract

The 13th international conference on spectral line shapes. AIP Conference Proceedings, Volume 386, pp. 231-232 (1997).

Physics

Intramolecular Energy Transfer, Intramolecular Dynamics, Dynamics Of Van Der Waals Molecules, Perturbation Theory

Scientific paper

Based on the interaction energy of two particles and calculations for hydrogen (1), the constant of the interaction law is calculated for a wide range of atoms. It is done by generalising an approach with quantum mechanical perturbation theory in its dipole approximation for neutral atoms. The atoms are modelled by a meta particle, which has the same dipole moment as the real atom. Two major cases are considered: the general case for symmetric atoms and the self resonance case. The constant is given numerically for mercury.

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