Theory of pure rotational transitions in doubly degenerate torsional states of ethane

Details Theory of pure rotational transitions in doubly degenerate torsional states of ethane Theory of pure rotational transitions in doubly degenerate torsional states of ethane

Jun 1979

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979phrvl..42.1613r&link_type=abstract

Physical Review Letters, vol. 42, June 11, 1979, p. 1613-1616.

Physics

Nuclear Physics

5

Ethane, Forbidden Transitions, Molecular Rotation, Molecular Theory, Quantum Theory, Selection Rules (Nuclear Physics), Coriolis Effect, Hamiltonian Functions, Torsional Vibration

Scientific paper

It is shown that pure rotational transitions in doubly degenerate torsional states of C2H6 (with selection rules Delta K = 0, plus or minus 1) are made allowed by Coriolis interaction between torsion and dipole-allowed vibrations. Expressions are presented for integrated intensities from which strengths of lines in the millimeter region can be calculated.

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