Studies of the chemistry of vibrationally and electronically excited species in planetary upper atmospheres

Astronomy and Astrophysics – Astrophysics

Scientific paper

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Dipole Moments, Distribution (Property), Oxygen Ions, Radiative Lifetime, Transition Probabilities, Venus Atmosphere, Vibration, Earth (Planet), Fluorescence, Mars (Planet), Mars Atmosphere, Mass Spectrometers, Pioneer Venus Spacecraft, Planetary Ionospheres, Scattering, Venus (Planet)

Scientific paper

The vibrational distribution of O2(+) in the atmospheres of Venus and Mars was investigated to compare with analogous values in the Earth's atmosphere. The dipole moment of the Z(2) Piu - X(2) Pig transition of O2(+) is calculated as a function of internuclear distance. The band absorption oscillator strengths and band transition probabilities of the second negative system are derived. The vibrational distribution of O2(+) in the ionosphere of Venus is calculated for a model based on data from the Pioneer Venus neutral mass spectrometer.

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