Methyl chloride and isoprene emissions from tropical rain forest in Southeast Asia

Physics

Scientific paper

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Atmospheric Composition And Structure: Biosphere/Atmosphere Interactions (0426, 1610), Atmospheric Composition And Structure: Troposphere: Composition And Chemistry, Biogeosciences: Isotopic Composition And Chemistry (1041, 4870), Biogeosciences: Plant Ecology (1851), Atmospheric Composition And Structure: Geochemical Cycles (1030)

Scientific paper

Methyl chloride (CH3Cl) fluxes were investigated at leaf and forest-canopy scales in tropical forests in Malaysia. Screening of CH3Cl-emitting species showed that 21% of 117 tree species were CH3Cl emitters; the percentage was markedly higher for dipterocarps (66%) than non-dipterocarps (6%). The dipterocarp-derived CH3Cl was characterized by high emissions (median: 0.03 μg g-1 h-1) and low stable carbon isotope ratios (mean: -88.9 +/- 11.0‰). Measurements of CH3Cl above the canopy showed a slight decrease in the mixing ratios with increasing height. These values were used to estimate the canopy-scale flux of about 14 μg m-2 h-1, comparable to that extrapolated from the leaf-scale emissions. Using the canopy-scale flux, global CH3Cl emission by tropical forests was estimated to be 1.3 Tg yr-1, representing approximately 30% of the global emissions. Above-canopy measurements were also made for isoprene, with a mean flux of 1.2 mg m-2 h-1.

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