Tropospheric distribution and variability of N2O: Evidence for strong tropical emissions

Physics

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Atmospheric Composition And Structure: Biosphere/Atmosphere Interactions (0426, 1610), Atmospheric Composition And Structure: Constituent Sources And Sinks, Atmospheric Composition And Structure: Troposphere: Composition And Chemistry, Biogeosciences: Biosphere/Atmosphere Interactions (0315), Biogeosciences: Trace Gases

Scientific paper

Measurements of atmospheric N2O spanning altitudes from the surface to 14 km, and latitudes from 67°S to 85°N, show high concentrations in the tropics and subtropics, with strong maxima in the middle and upper troposphere. The pattern varies significantly over time scales of a few weeks. Global simulations do not accurately capture observed distributions with latitude, altitude, or time. Inversion results indicate strong, episodic inputs of nitrous oxide from tropical regions (as large as 1 Tg N-N2O over 9 weeks) are necessary to produce observed vertical and latitudinal distributions. These findings highlight strong tropical sources of N2O with high temporal variability, and the necessity of using full vertical profile observations in deriving emissions from atmospheric measurements.

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