Model studies of the D-region negative-ion composition during day-time and night-time

Physics

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D Region, Diurnal Variations, Ionospheric Composition, Negative Ions, Nitrogen Oxides, Photodissociation, Atmospheric Chemistry, Atmospheric Models, Electron-Ion Recombination, Vapor Phases

Scientific paper

A model for the negative-ion composition of the D-region is constructed, based on gas-phase reactions and photodissociation and photodetachment processes. The height distribution of negative-ion species, electrons and total positive ions for day-time and night-time are examined using time-dependent solutions of their continuity equations which incorporate simultaneous solutions for the minor neutral constituents involved. A distinction is drawn between the two isomers of NO3(-) and particle attention is paid to the influence of possible chemical and photodestruction of the more stable form of this ion.

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