Measurements of absolute line intensities in carbon dioxide bands near 5.2 microns

Physics – Optics

Scientific paper

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Carbon Dioxide, Infrared Spectra, Line Spectra, Molecular Spectra, Least Squares Method, Molecular Rotation, Spectral Bands, Vibrational Spectra

Scientific paper

A nonlinear least-squares spectral fitting procedure has been used to derive experimental absolute intensities for over 300 unblended lines belonging to twelve CO2 bands in the 5.2-micron region. The spectral data were recorded at 0.01/cm resolution and room temperature with the Fourier transform spectrometer in the McMath solar telescope complex at the National Solar Observatory on Kitt Peak and have a signal-to-rms noise ratio of 2000-4000. A natural sample of carbon dioxide was used as the sample gas. For each band, the measured line intensities have been analyzed to derive the vibrational band intensity and coefficients of the F factor. The results are compared to the values used to calculate the intensities in the 1982 Air Force Geophysics Laboratory line parameters compilation.

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