The geochemistry of the stable isotopes of chlorine

Physics

Scientific paper

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Scientific paper

A procedure for measuring small differences in ClCl 37 -Cl 35 ratios was developed. It was tested by measuring the chlorine isotope fractionation in the following isotopic exchange reactions: (a) ammonium chloride, hydrogen chloride; (b) solid sodium chloride, aqueous chloride ion; (c) chlorine, hydrogen chloride; (d) aqueous hexachloroplatinate (IV), chloride ion. The Cl 37 -Cl 35 ratio in eighty-one samples of natural occurrence was investigated. No significant variations in the ratio was observed. The results are discussed in terms of the geochemical cycle of chlorine.

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