Carbonyl sulfide (COS) measurements in the Arctic polar vortex

Physics

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Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry, Atmospheric Composition And Structure: Aerosols And Particles, Atmospheric Composition And Structure: Geochemical Cycles

Scientific paper

One stratospheric carbonyl sulfide (COS) vertical profile in the Arctic polar vortex has been retrieved from air samples collected by the MPAE balloon-borne cryogenic sampler on January 18, 1992, at Kiruna, Sweden. The measurements were made in the altitude range 7.5-28.5 km. The upper tropospheric volume mixing ratios of COS were 355+/-60 pptv. The stratospheric profile shows that COS is subject to considerable subsidence this time of the year. The lowest VMRs were encountered at around 20 km altitude, while above that height a COS increase was observed. A possible explanation could be reversible uptake of COS by frozen sulfuric acid aerosols.

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