Electrochemistry of cations in diopsidic melt - Determining diffusion rates and redox potentials from voltammetric curves

Details Electrochemistry of cations in diopsidic melt - Determining diffusion rates and redox potentials from voltammetric curves Electrochemistry of cations in diopsidic melt - Determining diffusion rates and redox potentials from voltammetric curves

Dec 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990gecoa..54.3353c&link_type=abstract

Geochimica et Cosmochimica Acta (ISSN 0016-7037), vol. 54, Dec. 1990, p. 3353-3367.

Physics

6

Cations, Diffusion Coefficient, Electric Potential, Electrochemistry, Redox Cells, Volt-Ampere Characteristics, Melting, Metal Ions, Reaction Kinetics, Silicates

Scientific paper

Results are presented on determinations of reduction potentials and their temperature dependence of selected ions in diopsidic melt, by using linear sweep voltammetry. Diffusion coefficients were measured for cations of Eu, Mn, Cr, and In. Enthalpies and entropies of reduction were determined for the cations V(V), Cr(3+), Mn(2+), Mn(3+), Fe(2+), Cu(2+), Mo(VI), Sn(IV), and Eu(3+). Reduction potentials were used to study the structural state of cations in the melt.

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