Assignments of autoionization states of O2-asterisk

Details Assignments of autoionization states of O2-asterisk Assignments of autoionization states of O2-asterisk

Jan 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jqsrt..37....1w&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 37, Jan. 1987, p. 1-15.

Physics

29

Autoionization, Extreme Ultraviolet Radiation, Oxygen, Photoionization, Quantum Numbers, Rydberg Series, Franck-Condon Principle, Optical Emission Spectroscopy, Ultraviolet Lasers, Vibrational Spectra

Scientific paper

Attention is given to the uncertainties that remain concerning the autoionization states of O2 leading to the a 4Pi(u) and A 2Pi(u) states of O2(+), as well as some of the assignments of the autoionization states and the determinations of effective quantum numbers and quantum defects. The former problems of vibrational assignments are unambiguously established in view of a study of isotopic oxygen molecules. A systematic examination of the known Rydberg series is conducted, and new assignments and interpretations for several autoionization states leading to the various states of O2(+) are suggested.

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