Sub-Doppler Spectroscopy of the A^1B_1 - X^1A_1 Electronic Transition of CBr_2

Details Sub-Doppler Spectroscopy of the A^1B_1 - X^1A_1 Electronic Transition of CBr_2 Sub-Doppler Spectroscopy of the A^1B_1 - X^1A_1 Electronic Transition of CBr_2

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confetg13a&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Electronic (Uv/Vis/Nir)

Scientific paper

Sub-Doppler spectra of selected bands of the ~A^1B_1 - ~X^1A_1 transition of CBr_2 are presented allowing all three rotational constants to be determined for the zero point level of the ground state for the first time. Refined rotational constants are presented for various ~A state vibrational levels, and an additional progression is identified in the ~A-~X absorption spectrum. The assignment of this progression was assisted by modelling Franck-Condon factors with the PGOPHER program.
E.H. Al-Samra and C.M. Western, J. Mol. Spectrosc. (2010), In Press, doi:10.1016/j.jms.2010.02.001
PGOPHER, a Program for Simulating Rotational Structure, C. M. Western, University of Bristol, http://pgopher.chm.bris.ac.uk

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