Fourier Transform Microwave Spectrum of AlCCH (X1Σ^+) and its 13C/D Isotopologues

Details Fourier Transform Microwave Spectrum of AlCCH (X1Σ^+) and its 13C/D Isotopologues Fourier Transform Microwave Spectrum of AlCCH (X1Σ^+) and its 13C/D Isotopologues

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confemh06s&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Mini-Symposium: Metal Containing Molecules

Scientific paper

The microwave spectrum of AlCCH (X1Σ^+) has been measured using Fourier transform microwave (FTMW) techniques in the frequency range of 9-40 GHz. This molecule was created in a supersonic expansion by the reaction of trimethyl aluminum, Al(CH_3)_3, and acetylene, C_2H_2, or methane, CH_4, diluted in argon carrier gas, using a pulsed nozzle coupled with a dc discharge. Spectra of Al12C13CH, Al13C12CH, Al13C13CH, Al12C12CD have also been recorded. From these data, rotational constants and Al and D hyperfine parameters have been determined, as well as the r_m(1) structure. AlCCH is a model system for heteroatom dicarbide species.

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