Relativistic effects in two valence electron atoms and ions and the search for variation of the fine structure constant

Physics – Atomic Physics

Scientific paper

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Scientific paper

10.1103/PhysRevA.70.014102

We perform accurate calculations of the dependence of transition frequencies in two valence electron atoms and ions on a variation of the fine structure constant, alpha. The relativistic Hartree-Fock method is used with many-body perturbation theory and configuration interaction methods to calculate transition frequencies. The results are to be used in atomic-clock-type laboratory experiments designed to test whether alpha varies in time.

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