NO/+/ and water cluster ions in the D-region

Details NO/+/ and water cluster ions in the D-region NO/+/ and water cluster ions in the D-region

Jan 1976

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1976jatp...38...61t&link_type=abstract

Journal of Atmospheric and Terrestrial Physics, vol. 38, Jan. 1976, p. 61-67.

Physics

2

Atmospheric Chemistry, D Region, Hydronium Ions, Molecular Ions, Nitric Oxide, Atmospheric Moisture, Molecular Collisions, Photoionization, Vertical Distribution, Water

Scientific paper

A positive-ion model for the daytime D-region is used to examine the formation of water cluster ions when NO(+) is the major ion produced by photoionization. Particular attention is paid to the role of NO(+).CO2 and NO(+).N2 in the NO(+) hydration processes and to the importance of collisional dissociation of these ions. It is found that with rate coefficients for these dissociation processes based on laboratory measurements, the computed results are not consistent with measurements of ion composition and electron concentrations.

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