Solid carbon dioxide in a natural diamond

Physics

Scientific paper

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Carbon Dioxide, Diamonds, Absorption Spectra, Infrared Spectra

Scientific paper

The discovery of solid CO2 in a natural diamond is reported. Infrared spectroscopy indicates that the CO2 is presently at a pressure of 5 GPa and must therefore have been trapped at even greater pressures in the hot mantle, corresponding to depths of about 220-270 km. At these pressures, free CO2 should react with olivine and pyroxene; thus, its survival indicates the presence at depth of an environment of different mineralogy such a a fully carbonated metasomatic vein or a block of subducted sediments.

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