FTIR Study of Tricarbon Hydrides in Solid Argon at 10 K.

Details FTIR Study of Tricarbon Hydrides in Solid Argon at 10 K. FTIR Study of Tricarbon Hydrides in Solid Argon at 10 K.

Jan 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990phdt........63h&link_type=abstract

Thesis (PH.D.)--TEXAS CHRISTIAN UNIVERSITY, 1990.Source: Dissertation Abstracts International, Volume: 51-08, Section: B, page:

Physics

1

Scientific paper

An FTIR study of tricarbon hydrides has been carried out by trapping the products of the vacuum uv photolysis of methylacetylene, allene, cyclopropane, and their deuterated precursors, in solid argon at 10 K. Stable, partially deuterated tricarbon hydride molecules have been identified, based on available matrix and gas phase data and by using the Wilson GF matrix method to determine the vibrations of partially deuterated isotomers of the molecules. The results reveal new information on the vibrations for 10 species of tricarbon hydrides, including two C _3H isomers, linear C_3H (propenylidyne) and cyclic C_3H; five C_3H_2 isomers, cyclopropenylidene, vinylidenecarbene, propargylene, trans-propenediylidene, and cis-propenediylidene; two C _3H_3 isomers, propargyl and cyclopropenyl; and one C_3 H_5 isomer, allyl. (Abstract shortened with permission of author.).

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