Proton excitation of fine-structure transitions in Fe XIV

Physics – General Physics

Scientific paper

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Atomic Energy Levels, Atomic Excitations, Electron Transitions, Fine Structure, Iron, Proton Impact, Born Approximation, Elastic Scattering, Hydrogen Ions, Potential Energy, Scattering Cross Sections

Scientific paper

The interaction of a proton with Fe(13+) is characterized for all distances by calculating the potential-energy curves of FeH(14+) via an approximation which sufficiently describes the short-range interaction while taking the quadrupole and polarization forces into account for the long-range interaction. Interaction potentials are determined for the quasimolecular Sigma and Pi states and used to compute the quantal cross sections of Fe(13+) proton-impact excitation. Comparison of the quantal cross sections and rate coefficients with those based on Coulomb-Born and elastic approximations indicates that the latter are often misleading, and that the quantal approach provides the most accurate characterization of the potentials available.

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