Dissociative recombination of electrons with NO(+) ions

Details Dissociative recombination of electrons with NO(+) ions Dissociative recombination of electrons with NO(+) ions

Jun 1983

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983p%26ss...31..667b&link_type=abstract

Planetary and Space Science (ISSN 0032-0633), vol. 31, June 1983, p. 667-670. DARPA-supported research.

Physics

16

Dissociation, Electron-Ion Recombination, Ionic Collisions, Nitrogen Oxides, Recombination Coefficient, Resonance Scattering, Afterglows, Charge Distribution, Electron Energy, Ionospheric Electron Density, Trapped Particles, Upper Atmosphere

Scientific paper

Resonant scattering theory is applied to the calculation of the rate of dissociative recombination in e-NO(+) collisions. For ground state ions at 300 K, the recombination rate is 4.3 x 10 to the 7th cu cm/s, in good agreement with the afterglow data. At higher electron temperatures, the calculated rate lies between the values measured in afterglow and trapped-ion experiments. A possible explanation of this discrepancy is offered. For vibrationally excited ions, the recombination coeffcient is significantly lower than that of the ground state.

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