Apatite, phosphorus and titanium in eclogitic garnet from the upper mantle

Physics

Scientific paper

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Calcium Phosphates, Earth Mantle, Garnets, Geochemistry, Metamorphic Rocks, Minerals, Phosphorus, Titanium, Basalt, Chondrites, Eclogite, Metamorphism (Geology), Solubility

Scientific paper

The existence of apatite exsolution lamellae in garnet supports earlier suggestions that garnet is a major repository for P in the mantle, and that P is strongly coupled to Na+Ti. The bulk P content (approximately 250 ppm) of mantle eclogites is unexpectedly similar to estimates for the P content (130-220 ppm) of the upper mantle; both rocks are depleted relative to chondrites and to ocean floor basalts. Eclogites have either equilibrated with the mantle at large, or have undergone secondary melting, and based on P contents are unlikely to have had subducted protoliths.

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