Recent progress in the determination of interatomic potentials of alkali-argon systems

Details Recent progress in the determination of interatomic potentials of alkali-argon systems Recent progress in the determination of interatomic potentials of alkali-argon systems

Apr 1999

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999aipc..467..395z&link_type=abstract

The 14th international conference on spectral line shapes. AIP Conference Proceedings, Volume 467, pp. 395-399 (1999).

Physics

1

Potential Energy Surfaces For Collisions, Fluorescence And Phosphorescence Spectra

Scientific paper

The present status of determination of internuclear potentials from laser spectroscopic data is reviewed for LiAr, NaAr, and KAr. An improved potential is given for the X 2Σ state of NaAr. For the first time, we were able to deduce the R dependence of the molecular spin-orbit operator directly from spectroscopic data for the case of the A 2Π state of KAr. In addition, an interatomic potential has been obtained for the B 2Σ state of KAr with Re=8.0 Å and De=9.7 cm-1 as preliminary values for the equilibrium parameters.

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