Optical Radio-Frequency Double Resonance in Molecules: The OH Radical

Details Optical Radio-Frequency Double Resonance in Molecules: The OH Radical Optical Radio-Frequency Double Resonance in Molecules: The OH Radical

Nov 1969

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1969phrvl..23.1207g&link_type=abstract

Physical Review Letters, vol. 23, Issue 21, pp. 1207-1209

Physics

17

Scientific paper

The g values for the two hyperfine components of the J'=32, K'=2, v'=0 level of the A2Σ+ state of OH have been determined using the technique of optical radio-frequency double resonance. They are found to be g(F=2)=0.301+/-0.0015 and g(F=1)=0.492+/-0.0045 in agreement with the values calculated assuming Hund's case (b) coupling. From our earlier measurement of gτ for this state, the radiative lifetime is found to be (7.7+/-0.8) × 10-7 sec, corresponding to a band oscillator strength f00=(9.3+/-1.0)×10-4.

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