Rotational intensity factors for 2Σ - 4Σ transitions in diatomic molecules.

Physics

Scientific paper

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Molecular Processes

Scientific paper

Expressions are given for rotational intensity factors for the spin-forbidden transitions 2Σ± - 4Σ± (int) and 2Σ± - 4Σ-+ (int) in diatomic molecules. These formulae are valid for non-zero values of the spin-splitting parameter λ of the 4Σ state.

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