High pressure and high temperature fluid fugacities

Details High pressure and high temperature fluid fugacities High pressure and high temperature fluid fugacities

Apr 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987gecoa..51..783s&link_type=abstract

Geochimica et Cosmochimica Acta (ISSN 0016-7037), vol. 51, April 1987, p. 783-791. Research supported by the City University of

Physics

19

Equations Of State, Gibbs Free Energy, High Pressure, High Temperature, Phase Diagrams, Shock Waves, Carbon Dioxide, Earth Mantle, Thermochemistry, Water

Scientific paper

Available high-temperature and high-pressure shock wave data on fluids are combined with low-temperature and low-pressure data to generate empirical equations of state in the virial format in reduced pressure and temperature for many species. A similar equation of state is derived for H2O. The fugacities of the pure species in the C-H-O system can be calculated using the present equation to a temperature of 3000 K and to a pressure of 1 megabar. It is noted that dissociation of the pure species may invalidate the data over certain pressure-temperature ranges.

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