Physics
Scientific paper
Jun 1998
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1998aipc..430..241h&link_type=abstract
The eleventh international conference on fourier transform spectroscopy. AIP Conference Proceedings, Volume 430, pp. 241-244 (1
Physics
1
Effects Of Air Pollution, Effects Of Clouds And Water, Ice Crystal Phenomena
Scientific paper
Partial least squares (PLS) regression has been evaluated as a robust calibration technique for over 100 hazardous air pollutants (HAPs) measured by open path Fourier transform infrared (OP/FT-IR) spectrometry. PLS has the advantage over the current recommended calibration method of classical least squares (CLS), in that it can look at the whole useable spectrum (700-1300 cm-1, 2000-2150 cm-1, and 2400-3000 cm-1), and detect several analytes simultaneously. Up to one hundred HAPs synthetically added to OP/FT-IR backgrounds have been simultaneously calibrated and detected using PLS. PLS also has the advantage in requiring less preprocessing of spectra than that which is required in CLS calibration schemes, allowing PLS to provide user independent real-time analysis of OP/FT-IR spectra.
Griffiths Peter R.
Hart Brian K.
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