Variations in the sign of the pressure-induced lineshifts in the ν2 band of ammonia with temperature.

Details Variations in the sign of the pressure-induced lineshifts in the ν2 band of ammonia with temperature. Variations in the sign of the pressure-induced lineshifts in the ν2 band of ammonia with temperature.

Jun 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jqsrt..55..741b&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 55, issue 6, pp. 741-743

Physics

4

Ammonia: Line Profiles, Ammonia: Line Broadening, Ammonia: Molecular Processes

Scientific paper

The self-collisional shift of the aP(6,0) and aP(6,1) lines of the infrared ν2 ammonia band was measured as a function of temperature in the range 200-400 K. In agreement with theoretical predictions, the shift goes from negative (red shift) to positive (blue shift) with increasing temperature. Such a result must be taken into account in modelling the temperature dependence of pressure shift.

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