Self- and foreign-gas collision shifting in the ammonia inversion spectrum

Details Self- and foreign-gas collision shifting in the ammonia inversion spectrum Self- and foreign-gas collision shifting in the ammonia inversion spectrum

Jul 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jqsrt..48..115c&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 48, no. 1, July 1992, p. 115-117. Research su

Physics

Ammonia, Frequency Shift, Molecular Collisions, Molecular Spectra, Population Inversion, Electron Transitions, Electronic Spectra, Temperature Effects

Scientific paper

The shift parameters for both self- and foreign-gas-broadened lines in the ammonia-inversion spectrum are calculated using the many-level convergent approach developed by Cattani (1990). Good agreement between theory and experiment is noted in the NH3-NH3 and NH3-OCS cases, and the results confirm the importance of both inversion and rotational transitions in lineshift estimates.

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