Rates of Hydrothermal Reactions

Physics

Scientific paper

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Scientific paper

The rates of reactions of silicates and aqueous fluids follow zero-order kinetics controlled by the reacting surface area with the rate constant given by the equation: log k/bumpeq -2900/T - 6.85, where T is temperature and where k has the unit's gram-atoms of oxygen per square centimeter per second. This expression appears to hold for all silicates and for reactions involving dissolution, fluid production, or solid-solid transformations in the presence of a fluid of moderate to high pH.

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