The far-infrared spectrum of hydrogen sulfide - The (000) rotational constants of (H-32)2S, (H-33)2S, and (H-34)2S

Details The far-infrared spectrum of hydrogen sulfide - The (000) rotational constants of (H-32)2S, (H-33)2S, and (H-34)2S The far-infrared spectrum of hydrogen sulfide - The (000) rotational constants of (H-32)2S, (H-33)2S, and (H-34)2S

Oct 1983

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983cajph..61.1462f&link_type=abstract

Canadian Journal of Physics (ISSN 0008-4204), vol. 61, Oct. 1983, p. 1462-1473. Research supported by the Universitede Paris VI.

Physics

59

Far Infrared Radiation, Gas Giant Planets, Hydrogen Sulfide, Molecular Rotation, Molecular Spectra, Planetary Atmospheres, Atmospheric Chemistry, Constants, High Resolution, Hydrogen Isotopes, Rotational Spectra

Scientific paper

The pure rotation spectrum of hydrogen sulfide was investigated between 50 and 320/cm using a Fourier transform spectrometer at an apodized resolution of 0.005/cm. High resolution and a good signal-to-noise ratio were obtained which results in a significant improvement in the accuracy of the wavenumbers of the rotational transitions of the three isotopic species (H-32)2S, (H-33)2S, and (H-34)2S that were observed in natural abundance. These rotational transitions and the available microwave data were analyzed using the least squares fit technique in order to determine the precise rotational constants for each isotopic species. These constants were also employed in order to calculate precisely the absorption of natural hydrogen sulfide in the far-infrared region of the spectrum.

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