Origin of Trace Elements in Spinel from Ca-Al-rich Inclusions: Constraints from NanoSIMS Analyses of Spinel and Enclosing Melilite

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Scientific paper

Ti valence state changes during initial crystallization appears to be
the most plausible explanation for the center peaked Ti zoning profiles
in spinel. Preliminary NanoSIMS analysis did not reveal any direct
evidence for diffusion of trace elements from spinel to the melilite.

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