Nitrogen-induced absorption of oxygen in the Herzberg continuum

Physics

Scientific paper

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Herzberg Bands, Nitrogen, Oxygen Spectra, Photoabsorption, Ultraviolet Spectra, Continuous Spectra, Solar Radiation, Stratosphere

Scientific paper

Total absorption of O2 induced by collisions with N2 has been measured at room temperature in the Hersberg continuum using a one meter normal incidence grating monochromator. The enhanced absorption is ascribed to the formation of O2-O2 and O2-N2 dimers. The interaction constants for these dimers are determined and utilized to investigate their effect on the absorption of solar radiation in the stratosphere.

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