Spontaneous mirror symmetry breaking via enantioselective autocatalysis

Details Spontaneous mirror symmetry breaking via enantioselective autocatalysis Spontaneous mirror symmetry breaking via enantioselective autocatalysis

Jul 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996aipc..379..141a&link_type=abstract

Physical orgin of homochirality in life. AIP Conference Proceedings, Volume 379, pp. 141-150 (1996).

Physics

Specific Chemical Reactions, Reaction Mechanisms, Optical Activity, Optical Rotation, Circular Dichroism

Scientific paper

The conditions for spontaneous generation of optically active product under autocatalytic type reactions is considered on the base of the general kinetic model of enantioselective autocatalytic stages. It is shown that the spontaneous generation of optical activity mostly depends on the enantioselectivity of catalytic transformations. The properties of autocatalytic reactions, which are needed for an experiment, as well as the necessary chemical conditions, are discussed.

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