Effects of CO2 on the phase behavior of the enstatite-forsterite system at high pressures and temperatures

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The effect of CO2 on the various phase transitions in the enstatite (MgSiO3)-forsterite (Mg2SiO4) system observed at high pressures and high temperatures is investigated on the basis of the available experimental results and the zero-pressure density data for all the phases. Except for the coexistence with magnesite and stishovite, the high-pressure phase transition scheme for the MgSiO3-CO2 system remains very much the same as for pure enstatite when CO2 <30.48wt.%. The transformation scheme for the Mg2SiO4-CO2 system, however, becomes rather complicated when minute amounts of CO2 are present. Not only the ordinary high-pressure modifications of Mg2SiO4 (e.g., β-phase and spinel modification) are present, but those of MgSiO3 and SiO2 plus magnesite are also present in the Mg2SiO4-CO2 system. It has also been found that all the high-pressure phase transitions known in MgSiO3 should not occur when CO2 >=30.48wt.%, and that all those known in Mg2SiO4 should not occur when CO2 >=38.48wt.%. With the presence of a small amount of CO2, the number of high-pressure phase transitions in the Mg2SiO4-CO2 system is about twice as that found in forsterite, and the increase in density associated with each transition in both forsterite and enstatite is reduced.

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