Electric field gradients from NMR measurements on the Si(111)3 × 1-Li reconstruction

Physics

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Scientific paper

The Li-induced formation of the 3 × 1 reconstruction of the Si(111) surface has been investigated by nuclear magnetic resonance (NMR) on the Li nuclei. Two different electric field gradients (EFGs) were observed simultaneously and could be assigned to the EFG of Li adsorbed on Si(111)7 × 7 and Li involved in the 3 × 1 reconstruction. The observed EFGs are positive, indicating a Li adsorption site not above but rather within the reconstruction. The implications of these findings on some of the proposed structural models of the 3 × 1 reconstruction are discussed.

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