Overpotentials produced by Films of Hydrogen less than one Molecule thick

Details Overpotentials produced by Films of Hydrogen less than one Molecule thick Overpotentials produced by Films of Hydrogen less than one Molecule thick

Aug 1928

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1928natur.122..170m&link_type=abstract

Nature, Volume 122, Issue 3066, pp. 170-171 (1928).

Physics

Scientific paper

IN the course of recent work in the Physical Laboratory of this University on hydrogen overpotential at a mercury cathode, large changes of electrode potential were found to take place, and considerable over-potential was produced with depositions of hydrogen corresponding to very much less than a monomolecular layer. It was felt that these observations were of considerable interest, as they showed that, for the overpotential so obtained, any theory requiring gas in bulk (such as a surface tension theory, or one requiring a continuous film offering resistance to the current) would be untenable.

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