Rotational line-strengths in the 3Σ± - 3Σ- orbitally forbidden electric dipole transitions.

Details Rotational line-strengths in the 3Σ± - 3Σ- orbitally forbidden electric dipole transitions. Rotational line-strengths in the 3Σ± - 3Σ- orbitally forbidden electric dipole transitions.

May 1991

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991jqsrt..45..283b&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 45, issue 5, pp. 283-289

Physics

3

Scientific paper

Expressions have been developed for the branch intensity factors of orbitally forbidden electric dipole transitions of the type 3Σ± - 3Σ- in diatomic molecules. It is shown that, in general, the line intensities are governed by the following 13 transition moments: three vibronic moments reflecting spin-orbit effects, six rovibronic moments due to orbit-rotation interaction and four higher-order cross-moments of relatively smaller magnitude. Some special cases are discussed and a few useful sum rules of general validity are established.

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