The Pfi-Zeke Spectroscopy Study of HfS+ and the Ionization Energy of HfS

Details The Pfi-Zeke Spectroscopy Study of HfS+ and the Ionization Energy of HfS The Pfi-Zeke Spectroscopy Study of HfS+ and the Ionization Energy of HfS

Jun 2011

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2011mss..confewg06a&link_type=abstract

"International Symposium On Molecular Spectroscopy, 66th Meeting, Held 20-24 June, 2011 at Ohio State University. http://molspec

Physics

Electronic

Scientific paper

Spectroscopic data for the ground and low-lying states HfS+ have been obtained using the technique of pulse field ionization - zero electron kinetic energy (PFI-ZEKE) spectroscopy. PFI-ZEKE spectra were recorded for the levels X2Σ+ (v=0-18), 2Δ5/2 (v=0-8) and 2Δ3/2 (v=0-3). Assignments of the electronically excited states of HfS+ are based on CCSD(T) and DFT calculations with SDB-aug-cc-pVTZ basis set. Rotationally resolved spectra were recorded for the X2Σ+ (v=0) state using single rotational line excitation of the intermediate state. The ionization energy for HfS, term energies and molecular constants for the ground and low-lying states of HfS+ will be reported.

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