New Bands of Nickel Fluoride in the Near Infrared by Intracavity Laser Absorption Spectroscopy

Physics

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Electronic

Scientific paper

Several new electronic transitions of NiF with red-degraded bandheads near 12896 and 13497 wn were recorded and analyzed. All bands have a common lower level: namely, v=0 of the A 2Δ5/2 state. The observed 58NiF and 60NiF isotopologue splitting in each band suggests tentative assignments as the (3,0) and (2,0) vibrational bands of the [12.6]Ω=5/2 - A 2Δ5/2 transition and the (2,0) band of a new [13.1]Ω=5/2 - A 2Δ5/2 transition of NiF. Results of the analysis will be presented. The gas phase NiF molecules were produced using a nickel-lined hollow cathode in an argon-based electric discharge with a small amount of SF6.

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