Water partitioning in the Earth's mantle

Physics

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Scientific paper

We have conducted H 2 O partitioning experiments between wadsleyite and ringwoodite and between ringwoodite and perovskite at 1673 K and 1873 K, respectively. These experiments were performed in order to constrain the relative distribution of H 2 O in the upper mantle, the mantle transition zone, and the lower mantle. We successfully synthesized coexisting mineral assemblages of wadsleyite-ringwoodite and ringwoodite-perovskite that were large enough to measure the H 2 O contents by secondary ion mass spectrometry (SIMS). Combining our previous H 2 O partitioning data ( Chen et al., 2002 ) with the present results, the determined water partitioning between olivine, wadsleyite, ringwoodite, and perovskite under H 2 O-rich fluid saturated conditions are 6:30:15:1, respectively. Because the maximum H 2 O storage capacity in wadsleyite is ˜3.3 wt% (e.g. Inoue et al., 1995 ), the possible maximum H 2 O storage capacity in the olivine high-pressure polymorphs are as follows: ˜0.7 wt% in olivine (upper mantle just above 410 km depth), ˜3.3 wt% in wadsleyite (410-520 km depth), ˜1.7 wt% in ringwoodite (520-660 km depth), and ˜0.1 wt% in perovskite (lower mantle). If we assume ˜0.2 wt% of the H 2 O content in wadsleyite in the mantle transition zone estimated by recent electrical conductivity measurements (e.g. Dai and Karato, 2009 ), the estimated H 2 O contents throughout the mantle are as follows; ˜0.04 wt% in olivine (upper mantle just above 410 km depth), ˜0.2 wt% in wadsleyite (410-520 km depth), ˜0.1 wt% in ringwoodite (520-660 km depth) and ˜0.007 wt% in perovskite (lower mantle). Thus, the mantle transition zone should contain a large water reservoir in the Earth's mantle compared to the upper mantle and the lower mantle.

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