Vibrational spectroscopy of H2+: hyperfine structure of two-photon transitions

Details Vibrational spectroscopy of H2+: hyperfine structure of two-photon transitions Vibrational spectroscopy of H2+: hyperfine structure of two-photon transitions

2008-06-12

arxiv.org/abs/0806.2049v1

Physical Review A: Atomic, Molecular and Optical Physics 77, 6 (2008) 063410

Physics

Quantum Physics

Scientific paper

10.1103/PhysRevA.77.063410

We present the computation of two-photon transition spectra between
ro-vibrational states of the H2+ molecular ion, including the effects of
hyperfine structure and excitation polarization. The reduced two-photon matrix
elements are obtained by means of a variational method. We discuss the
implications of our results for high-resolution spectroscopy of H2+.

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