Physics – Chemical Physics
Scientific paper
2011-11-11
Physics
Chemical Physics
The following article has been accepted by Journal of Chemical Physics. After it is published, it will be found at http://jcp.
Scientific paper
We perform a systematic investigation of the resonance and vibrational properties of naphthyl-terminated sp carbon chains (dinaphthylpolyynes) by combined multi-wavelength resonant Raman (MWRR) spectroscopy, ultraviolet-visible spectroscopy, and Fourier-transform infrared (FT-IR) spectroscopy, plus ab initio density functional theory (DFT) calculations. We show that the MWWR and FT-IR spectroscopies are particularly suited to identify chains of different lengths and different terminations, respectively. By DFT calculations, we further extend those findings to sp carbon chains end-capped by other organic structures. The present analysis shows that combined MWRR and FT-IR provide a powerful tool to draw a complete picture of chemically stabilized sp carbon chains.
Castelli Ivano Eligio
Cataldo Franco
Cinquanta Eugenio
Manini Nicola
Milani Paolo
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