Velocity-Mapped Ion Imaging of Methyl Nitrite Photodissociation

Details Velocity-Mapped Ion Imaging of Methyl Nitrite Photodissociation Velocity-Mapped Ion Imaging of Methyl Nitrite Photodissociation

Jun 2010

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confera08w&link_type=abstract

"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec

Physics

Dynamics

Scientific paper

Methyl nitrite, CH3ONO, was photodissociated at 355 nm in a velocity-map ion imaging apparatus. The NO photoproduct was detected through state-resolved 1+1' resonance-enhanced multiphoton ionization. The NO products are highly oriented in the laboratory frame, indicating perpendicular transition and a prompt dissociation. The velocities of the NO products reveal that methyl nitrite undergoes rapid predissociation after 355 nm excitation.

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