Van der Waals molecules - Possible roles in the atmosphere

Details Van der Waals molecules - Possible roles in the atmosphere Van der Waals molecules - Possible roles in the atmosphere

May 1980

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1980georl...7..289c&link_type=abstract

Geophysical Research Letters, vol. 7, May 1980, p. 289-292.

Physics

5

Atmospheric Chemistry, Atmospheric Composition, Dimers, Intermolecular Forces, Van Der Waals Forces, Carbon Dioxide, Dynamic Characteristics, Infrared Absorption, Molecular Interactions, Nitrogen, Nonequilibrium Conditions, Oxygen, Water

Scientific paper

Atmospheric equilibrium number densities are estimated for the van der Waals molecules N2.N2, N2.O2, O2.O2, N2.CO2, O2.CO2, N2.H2O, O2.H2O, CO2.CO2, H2O.H2O, A.A, A.CO2, and A.H2O for the altitude range 5-90 km. It is concluded that number densities of atmospheric dimer species are appropriately given by equilibrium estimates, and that some are of the same order as minor, rather than trace constituents. Possible roles of van der Waals molecules in neutral and ionic termolecular reactions, as well as infrared absorption and emission in the natural atmosphere, are proposed and examined.

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