Van Der Waals Interaction for Strongly Interacting Liquids

Details Van Der Waals Interaction for Strongly Interacting Liquids Van Der Waals Interaction for Strongly Interacting Liquids

2011-10-15

arxiv.org/abs/1110.3412v3

Physics

General Physics

Revised with detailed expositions, 11 pages, 2 figure

Scientific paper

The origin of an attractive van der Waals (vdW) interaction between two identical neutral atoms is due to an approximately isotropic polarization, which has been solved exactly if the distance between the atoms is very large compared to atomic size. Therefore, by default the vdW interaction is always assumed to be long range. Here, we prove (i) the existence of a blue-shifting vdW interaction for both long and short distances, and (ii) the original vdW theory does not lead to an attractive interaction between two strongly interacting atoms with large non-isotropic polarization.

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