UV and VUV spectroscopy and photochemistry of small molecules in a supersonic jet

Physics

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Fluid Jets, Free Radicals, Ionization, Molecules, Photochemical Reactions, Resonance, Supersonic Flow, Ultraviolet Spectroscopy, Cooling, Spectral Line Width, Ultraviolet Absorption, Vapor Phases

Scientific paper

UV and VUV absorption and emission spectroscopy is used to probe jet cooled molecules, free radicals, and clusters in the gas phase. Due to efficient cooling inhomogeneous effects on spectral line widths are eliminated. Therefore from these spectra, both structural and dynamical information is obtained. The photoproducts of these reactions are probed by resonance enhanced multiphoton ionization.

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