UV absorption spectrum and absorption cross sections of COF2 at 296 K in the range 200-230 nm

Details UV absorption spectrum and absorption cross sections of COF2 at 296 K in the range 200-230 nm UV absorption spectrum and absorption cross sections of COF2 at 296 K in the range 200-230 nm

Feb 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992georl..19..281n&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 19, Feb. 7, 1992, p. 281-284. Research supported by CEC.

Physics

6

Absorption Cross Sections, Atmospheric Composition, Carbonyl Compounds, Fluorides, Photodissociation, Ultraviolet Spectra, Absorption Spectra, Carbon Monoxide, Chlorofluorocarbons, Fluorine

Scientific paper

The UV spectrum and the absorption cross sections of carbonyl fluoride (COF2) have been measured in the wavelength range 200-230 nm at 296 K with a resolution of 0.03 nm by diode array spectroscopy. Preliminary results of the determination of the quantum yield of COF2 at 193 nm and 296 K are presented. The new absorption cross sections and the new estimate of the quantum yield were used to calculate photodissociation rate constants at solar zenith angles ranging from 0 to 86 deg as a function of height (0-55 km).

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